Health & Environmental Research Online (HERO)


Print Feedback Export to File
8686409 
Journal Article 
Spectral analysis of the 1H, 19F and 13C N.M.R. spectra of fluorobenzene 
Page, TF, Jr 
1967 
Molecular Physics
ISSN: 0026-8976
EISSN: 1362-3028 
13 
523-532 
English 
An analysis of the N.M.R. spectra of both neat fluorobenzene and a 5 mole per cent solution of fluorobenzene in cyclohexane was done by transition assignment and curve fitting of the 1H and 19F spectra at 60·0 and 56·4 Mc/s, respectively. All of the 1H–1H and 1H-19F coupling constants and internal chemical shifts were obtained and found to be unique. The direct 13C-1H, 13C-19F and the 13C-C-19F couplings have been determined from the 13C spectrum of fluorobenzene at 15·085 Mc/s. Results obtained are compared with those reported earlier. Some features of the 6-spin fluorobenzene system and evidence for virtual coupling of the 19F and 1H nuclei are discussed. 1967, Taylor & Francis Group, LLC. All rights reserved.