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8687617 
Journal Article 
Chemical conversions of 2-alkoxyacroleins - Communication 3. Comparative reactivity of 2-aroxy- and 2-alkoxyacroleins 
Shostakovskii, MF; Keiko, NA; Chichkarev, AP; Vylegzhanin, ON 
1971 
1 
Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN: 0568-5230 
20 
12 
2576-2578 
English 
1. The possibility of producing 2-phenoxyacrolein on the basis of the Mannich reaction was demonstrated. 2. The carbon-carbon double bond of 2-phenoxyacrolein is less polarized than in 2-alkoxyacroleins; moreover, delocalization of the π-electrons, just as in the case of alkoxy substituents, proceeds in the direction of the β-carbon atom. 3. The rate constants of the reaction with alcohol were determined for 2-aroxy- and 2-alkoxyacroleins in a cyclohexane solution at 25°. 1972 Consultants Bureau.