Determination by the method of chemiluminescence of the rate constant of quadratic recombination of peroxide radicals in reactions with a low luminescence yield | Health & Environmental Research Online (HERO)

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HERO ID

8688371

Reference Type

Journal Article

Title

Determination by the method of chemiluminescence of the rate constant of quadratic recombination of peroxide radicals in reactions with a low luminescence yield

Author(s)

Belyakov, VA; Rafikova, VS

Year

1974

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Journal

Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN: 0568-5230

Volume

Issue

Page Numbers

2359-2365

Language

English

DOI

10.1007/BF00922110

Abstract

1. A chemiluminescence method of determining the rate constant of quadratic recombination of peroxide radicals in reactions with a low luminescence yield was proposed and theoretically substantiated. 2. The method was tested on hydrocarbons with strongly differing values of the luminescence yields: cumene, cyclohexane, and toluene. The values obtained for the rate constants are in good agreement with the literature data. 3. The proposed method was used to determine the rate constant of quadratic recombination of peroxide radicals of n-decane. 1975 Plenum Publishing Corporation.