Cyclic unsaturated compounds - Communication 55. Isomeric transformations of 1,3- and 1,4-cyclohexadienes in the presence of bases | Health & Environmental Research Online (HERO)

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HERO ID

8688486

Reference Type

Journal Article

Title

Cyclic unsaturated compounds - Communication 55. Isomeric transformations of 1,3- and 1,4-cyclohexadienes in the presence of bases

Author(s)

Mironov, VA; Fedorovich, AD; Akhrem, AA

Year

1974

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Journal

Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN: 0568-5230

Volume

Issue

Page Numbers

1260-1264

Language

English

DOI

10.1007/BF00923092

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-34250415066&doi=10.1007%2fBF00923092&partnerID=40&md5=89d4a1e1c896ca95971ed8e698388a92
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Abstract

1. The cyclohexadienyl anion is formed when 1,3-cyclohexadiene (I) and 1,4-cyclohexadiene (II) are reacted with sodium amide in liquid ammonia, which under the experimental conditions is converted to a mixture of benzene and cyclohexane. 2. The isomerization of dienes (I) and (II) into each other under the influence of potassium tertbutylate in tert-butanol, or potassium tert-amylate in tert-amyl alcohol, leads to mixtures of the mentioned dienes, which are not thermodynamic equilibrium mixtures. 1974 Consultants Bureau.