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8702759 
Journal Article 
Kinetic determination of bond energy with chromium oxide catalyst 
Tolstopiatova, AA; Balandin, AA; Karpeiskaia, EI 
1958 
1 
Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN: 0568-5230 
7 
10 
1142-1149 
English 
1. The kinetics of dehydrogenation and dehydration of isopropyl alcohol on chromium oxide, prepared by heating ammonium bichromate, were studied. The relative adsorptional coefficients of acetone and hydrogen were determined. 2. Activation energies were determined for the following reactions: dehydrogenation and dehydration of isopropyl alcohol and dehydrogenation of cyclohexane. 3. Bond energies of the reacting atoms in the molecule with the catalyst were determined. A comparison was made with the catalytic properties of chromium oxide prepared by other methods. 1959 Consultants Bureau Inc.