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HERO ID
8702793
Reference Type
Journal Article
Title
Conversions of cyclohexane on palladinized gumbrine under hydrogen pressure
Author(s)
Shuikin, NI; Minachev, KM; Ryashentseva, MA; Afanas'Eva, YA
Year
1961
Is Peer Reviewed?
1
Journal
Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN:
0568-5230
Volume
10
Issue
7
Page Numbers
1223-1226
Language
English
DOI
10.1007/BF01118760
URL
https://www.scopus.com/inward/record.uri?eid=2-s2.0-34250587098&doi=10.1007%2fBF01118760&partnerID=40&md5=525f7145bea1ee5f40455bf6992f41f9
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Abstract
1. In the presence of 0.5% Pd gumbrine catalyst treated with hydrogen sulfide, at 470°, 20 atm H2, v=1.0 hr-1, and H2:HC=5::1, cyclohexane forms 40.2% benzene and 22.7% methylcyclopentane. 2. The carrier, activated gumbrine, under the same conditions possesses a considerable isomerizing action toward contraction of the six-membered ring to a five-membered. 3. A method has been developed for the photometric quantitative determination of palladium in palladinized gumbrine catalysts. 1962 Consultants Bureau.
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