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HERO ID
8702875
Reference Type
Journal Article
Title
Viscosity and self-diffusion in benzene-cyclohexane mixtures
Author(s)
Collins, DA
Year
1964
Is Peer Reviewed?
Yes
Journal
Australian Journal of Chemistry
ISSN:
0004-9425
EISSN:
1445-0038
Volume
17
Issue
5
Page Numbers
516-521
Language
English
DOI
10.1071/CH9640516
URL
https://www.scopus.com/inward/record.uri?eid=2-s2.0-33748929952&doi=10.1071%2fCH9640516&partnerID=40&md5=8d722ada3b07f801b9999407d4ae921a
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Abstract
The self-diffusion coefficient of benzene in benzene-cyclohexane mixtures was measured at 15°, 25°, and 35°. Viscosities of the mixtures were measured at the same temperatures. The diffusion coefficient is a maximum, while the viscosity is a minimum at a mole fraction of benzene between 0.6 and 0.8. The activation energy for viscous flow is a minimum in the mole fraction range 0.6–0.8 of benzene. The excess viscosity and the excess activation energy of viscous flow are minimal at a mole fraction 0.5, the same composition at which the maxima occur in excess volume and heat mixing. The product Dη is a linear function of mole fraction. 1964 CSIRO. All rights reserved.
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