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HERO ID
8703433
Reference Type
Journal Article
Title
The solubility of gases in liquids I. The solubility of a series of fluorine-containing gases in several non-polar solvents
Author(s)
Wilhelm, E; Battino, R
Year
1971
Is Peer Reviewed?
1
Journal
Journal of Chemical Thermodynamics
ISSN:
0021-9614
Volume
3
Issue
3
Page Numbers
379-392
Language
English
DOI
10.1016/S0021-9614(71)80055-1
Abstract
The solubilities of CF3Cl and CF2Cl2 in n-heptane, n-octane, cyclohexane, benzene, and carbon tetrachloride, and additionally CF4 and SF6 in n-octane were determined in the temperature range 24 to 35 °C. The solubility, Gibbs free energy, enthalpy, and entropy of solution were calculated from the experimental results for 1 atm partial pressure of gas and 25 °C. These values were compared with results calculated using the scaled particle theory. The agreement was good. The scaled particle theory was also used to determine the Lennard-Jones (6-12) pair potential parameters for the solvents, yielding results which are in excellent agreement with literature values. 1971 Academic Press Inc. (London) Ltd. All rights reserved.
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