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HERO ID
8703544
Reference Type
Journal Article
Title
Study of free radical conversions of a polycarbonate based on 1,1-di-(4-hydroxyphenyl)cyclohexane (ilon) by the esr method
Author(s)
Davydov, EY; Ledneva, OA; Mikheev, YA; Toptygin, DY; Pariiskii, GB
Year
1973
Is Peer Reviewed?
1
Journal
Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN:
0568-5230
Volume
22
Issue
3
Page Numbers
523-526
Language
English
DOI
10.1007/BF00854016
Abstract
1. The interaction of ilon and chlorine atoms produced by the photoreduction of additions of ferric chloride, was investigated by the ESR method at 77°K. 2. Under the action of light, an impurity of ferric chloride may lead to destruction of the polymer with breakdown of the macromolecules at the carbonate groups and C-Ar bonds. 3. Chlorine atoms also strip H atoms from the cyclohexane ring of the macromolecule with the formation of substituted cyclohexyl radicals. 1973 Consultants Bureau.
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