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8707152 
Journal Article 
The molecular structure of 1,3,5-trithiane from electron diffraction 
Bencze, Z; Kucsman, A; Schultz, G; Hargittai, I 
1989 
Yes 
Acta Chemica Scandinavica
ISSN: 0904-213X
EISSN: 1902-3103 
43 
953-956 
English 
The molecular structure of 1,3,5-trithiane has been determined by gas-phase electron diffraction at 466 K nozzle temperature. The experimental data are consistent with the chair conformation of the molecule with C3v symmetry. The ring is considerably more puckered than that of cyclohexane. The following bond lengths (rg, bond angles and torsional angle were obtained: S-C 1.812 ± 0.004, C-H 1.114 ± 0.004 Å, C-S-C 99.1 ± 0.4, S-C-S 115.8±0.1, H-C-H 109.7 ± 1.2, S-C-S-C 65.2 ± 0.5°. 1989 Acta Chemica Scandinavica. All rights reserved.