Relation of the gas chromatographic retention indexes of isomeric alkylcyclohexenoate esters to their structure and conformation | Health & Environmental Research Online (HERO)

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Citation
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HERO ID

8711438

Reference Type

Journal Article

Title

Relation of the gas chromatographic retention indexes of isomeric alkylcyclohexenoate esters to their structure and conformation

Author(s)

Rudenko, BA

Year

1983

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Journal

Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN: 0568-5230

Volume

Issue

Page Numbers

1002-1005

Language

English

DOI

10.1007/BF00956154

Abstract

1. Retention indexes have been determined for 29 methyl esters of alkyl-substituted cyclohexanoic and cyclohexenoic acids on capillary columns with polar stationary phases. 2. The cyclohexenoate and cyclohexanoate esters with methyl substituents at position 2 may exist in a stable conformation with an axial carbomethoxy group; this permits gas chromatography to be used to ascertain the stable conformations of cyclohexane and cyclohexene derivatives. 1983 Plenum Publishing Corporation.