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8714244 
Journal Article 
Reactions of 1-methoxycarbonyl-3-cyclohexene and 3,4-epoxy-1-methoxycarbonyl-cyclohexane with tert-butoxy radical 
Zaitseva, VV; Narizhnaya, ON 
1996 
1 
Russian Journal of Organic Chemistry
ISSN: 1070-4280
EISSN: 1608-3393 
32 
4 
480-485 
English 
Reactions of 1-methoxycarbonyl-3-cyclohexene and 3,4-epoxy-1-methoxycarbonylcyclohexane (as a 63:37 mixture of trans and cis isomers or pure trans isomers) with tert-butoxy radical at 413 K yield oligomeric products. In the case of epoxy derivatives, 1-methoxycarbonyl-4-cyclohexen-3-ol, 1-methoxycarbonyl-4-cyclohexen-3-one, and 1-methoxycarbonyl-3-cyclohexanone are also formed. This set of products indicates that tert-butoxy radical abstracts a hydrogen atom from the 2-position of the cyclohexene ring and from the 2,3- or 4,5-positions of the cyclohexane ring. 1996 MAEe Cyrillic signΚ Hayκa/Interperiodica Publishing.