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HERO ID
8715130
Reference Type
Journal Article
Title
Trishomoaromatic dianions of 1,3,5-triboracyclohexanes
Author(s)
Lößlein, W; Pritzkow, H; Von Schleyer, PR; Schmitz, LR; Siebert, W
Year
2000
Is Peer Reviewed?
Yes
Journal
Angewandte Chemie (International Edition)
ISSN:
1433-7851
EISSN:
1521-3773
Volume
39
Issue
7
Page Numbers
1276-1278
Language
English
DOI
10.1002/(SICI)1521-3773(20000403)39:7<1276::AID-ANIE1276>3.0.CO;2-B
Abstract
A new trishomoarene is obtained by reduction of hexamethyl-1,3,5- triboracyclohexane with lithium in donor solvents. Addition of tetrahydropyran (THP) and [12]crown-4 yields crystalline tetramers (the structure of the tetrameric anion obtained with [12]crown-4 is shown). The B3 rings are aromatic.
Keywords
Ab initio calculations; Aromaticity
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