Health & Environmental Research Online (HERO)


Print Feedback Export to File
8716666 
Journal Article 
Reactions of triazacyclohexanes with CuCl2: Surprising formation of a dimer between two [CuCl2]- ions with an unsupported cuprophilic attraction 
Köhn, RD; Seifert, G; Pan, Z; Mahon, MF; Kociok-Köhn, G 
2003 
Yes 
Angewandte Chemie (International Edition)
ISSN: 1433-7851
EISSN: 1521-3773 
42 
7 
793-796 
English 
Cuprophilic interactions are observed be tween the two copper centers of the unprecedented dimer 2, the structure of which contains two associated [Cu1Cl2]-ions. The surrounding complex is derived from the internal reduction of the Cu" complex 1, which displays a cis-divacant octahedral coordination geometry. 
Copper; Heterocycles; N ligands; Oxidation; Structure elucidation