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HERO ID
8722902
Reference Type
Journal Article
Title
Gelation-assisted control over excitonic interaction in merocyanine supramolecular assemblies
Author(s)
Yagai, S; Ishii, M; Karatsu, T; Kitamura, A
Year
2007
Is Peer Reviewed?
Yes
Journal
Angewandte Chemie (International Edition)
ISSN:
1433-7851
EISSN:
1521-3773
Volume
46
Issue
42
Page Numbers
8005-8009
Language
English
PMID
17868165
DOI
10.1002/anie.200702263
Abstract
(Figure Presented) Gelling together: Merocyanine dyes possessing a cholesterol group as a gelforming auxiliary self-assemble into nanoscopic fibers in apolar cyclohexane and polar acetone to form organogels, showing dramatically distinct optical properties through exciton coupling. This dramatic change is a result of different chromophore packing arrangements within the nanoscopic fibers (see fluorescence microscopy images with photographs of the gels as insets). 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
Keywords
Exciton coupling; Merocyanine dyes; Self-assembly; Solvatochromism
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