Jump to main content
US EPA
United States Environmental Protection Agency
Search
Search
Main menu
Environmental Topics
Laws & Regulations
About EPA
Health & Environmental Research Online (HERO)
Contact Us
Print
Feedback
Export to File
Search:
This record has one attached file:
Add More Files
Attach File(s):
Display Name for File*:
Save
Citation
Tags
HERO ID
8790625
Reference Type
Journal Article
Title
Electro-active nanofibers of a tetrathiafulvalene derivative with amide hydrogen bonds as a dopant-free hole transport material for perovskite solar cells
Author(s)
Kaneko, R; Chowdhury, TH; Sugawa, K; Lee, JaeJ; Otsuki, Joe; Islam, A
Year
2019
Is Peer Reviewed?
1
Journal
Solar Energy
ISSN:
0038-092X
Volume
194
Page Numbers
248-253
DOI
10.1016/j.solener.2019.10.078
Web of Science Id
WOS:000502888500027
Abstract
A tetrathiafulvalene derivative containing two amide units for intermolecular hydrogen bonds (Bis-amide-TTF) was found to form supramolecular assemblies, in which intermolecular TTF cores were stacked with each other. The electrical conductivity of Bis-amide-TTF-based film was 1.28 x 10(-5) S cm(-1), which was greater than that of spiro-OMeTAD doped with t-butylpyridine and bis(trifluoromethane)sulfonimide lithium salt (8.37 x 10(-6) S cm(-1)). Bis-amide-TTF was applied as a hole transport material (HTM) for perovskite solar cells (PSCs). The Bis-amide-TTF film has a deeper HOMO level than that of spiro-OMeTAD, leading to an increased open-circuit voltage of the PSCs. The power conversion efficiency of 14.5% with a short-circuit current density (J(sc)) of 19.8 mA cm(-2), an open-circuit voltage (V-OC) of 1.11 V, and a fill factor (FF) of 66% was achieved for PSCs fabricated with the dopant-free Bis-amide-TTF-based HTM, which was comparable to that obtained with spiro-OMeTAD with the dopants (15.5%).
Keywords
Perovskite solar cells; Hole transport materials; Dopant free; Tetrathiafulvalene; Hydrogen bonds; Nanofibers
Home
Learn about HERO
Using HERO
Search HERO
Projects in HERO
Risk Assessment
Transparency & Integrity