Study of the kinetics of the thermal decomposition of chlorine-containing carbon-chain polymers | Health & Environmental Research Online (HERO)

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HERO ID

9088626

Reference Type

Journal Article

Title

Study of the kinetics of the thermal decomposition of chlorine-containing carbon-chain polymers

Author(s)

Berlin, AA; Aseeva, RM; Smutkina, ZS; Kasatochkin, VI

Year

1964

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Journal

Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN: 0568-5230

Volume

Issue

Page Numbers

1879-1883

Language

English

DOI

10.1007/BF00844480

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-34250603276&doi=10.1007%2fBF00844480&partnerID=40&md5=401e7e57973bfaf6f4a031ff36b68090
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Abstract

1. The influence of the structure of a chlorine-containing polymer on the kinetics of its thermal decomposition was demonstrated. 2. The polymers can be arranged in the following series with respect to increasing relative rate and decreasing activation energy of the decomposition process: polyvinyl chloride, chlorinated polyvinyl chloride, polyvinylidene chloride, copolymer of vinyl chloride with vinylidene chloride (activation energies equal to 33.5, 31.6, 28.7, and 27.5 kcal/mole, respectively). © 1965 Consultants Bureau.