Phase partition of acrylonitrile (AN) in vinylidene chloride (VDC)/water system and its effect on VDC-AN copolymer composition | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

10157523

Reference Type

Journal Article

Title

Phase partition of acrylonitrile (AN) in vinylidene chloride (VDC)/water system and its effect on VDC-AN copolymer composition

Author(s)

Zhou, S; Weng, Z; Huang, Z; Pan, Z

Year

1999

Is Peer Reviewed?

Yes

Journal

Chinese Journal of Chemical Engineering
ISSN: 1004-9541

Publisher

SPRINGER VERLAG

Location

BERLIN

Volume

Issue

Page Numbers

326-331

Language

English

Web of Science Id

WOS:000084217700006

URL

http://://WOS:000084217700006
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Abstract

Phase partition of acrylonitrile in the vinylidene chloride/water system at different temperature and under pressure was studied. A calculation method for average VDC-AN copolymer composition with AN phase partition considered was proposed. The calculated results are in good agreement with the experimental data nearly the entire conversion range. VDC-AN copolymer with narrower composition distribution can be prepared in the suspension process and interpreted with dynamic equilibrium of AN between the oil and water phases continuously.

Keywords

Acrylonitrile; Copolymer composition; Phase partition; Suspension copolymerization; Vinylidene chloride