Addition of 1,1,1-trichloroethane and 1,1,1,3-tetrachloropropane to substituted olefins in the presence of Fe(CO)5 and nucleophilic additives | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

9104014

Reference Type

Journal Article

Title

Addition of 1,1,1-trichloroethane and 1,1,1,3-tetrachloropropane to substituted olefins in the presence of Fe(CO)5 and nucleophilic additives

Author(s)

Chukovskaya, ET; Kuz'Mina, NA; Freidlina, RK

Year

1972

Is Peer Reviewed?

Journal

Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN: 0568-5230

Volume

Issue

Page Numbers

2053-2055

Language

English

DOI

10.1007/BF00854644

Abstract

1. 1,1,1,3-Tetrachloropropane and 1,1,1-trichloroethane add to vinyl acetate when the system Fe(CO)5 +(CH3)2NC6H5 is used to initiate the reaction. 2. 1,1,1,3-Tetrachloropropane adds to chloroprene when the reaction is initiated by the system Fe(CO)5+i-C5H11OH to give the 1,4-addition (70%) and 4,1-addition (30%) products. Both adducts exist in the Z and E forms, with a predominance of the Z isomer. © 1973 Consultants Bureau.