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977171 
Journal Article 
Synthesis, spectral, thermal and antimicrobial studies of oxomolybdenum(V) and dioxomolybdenum(VI) complexes with 2,3-dimethyl-1-phenyl-4-(5-chloro-2-hydroxy-4-methylphenylazo)-5-pyrazolone 
Nair, MLHK; Siji, VL 
2008 
Yes 
Journal of the Indian Chemical Society
ISSN: 0019-4522 
85 
6 
589-594 
English 
WOS:000258163900001 
Some novel oxomolybdenum(V) and dioxomolybdenum(VI) complexes of the formulae [MoO(CMCAAP)Cl(2)], [MoO(CMCAAP)(NCS)Cl], [MoO(CMCAAP)(NO(3))Cl], [MoO(CMCAAP)(ClO(4))Cl], [MoO(2)(CMCAAP)Cl], [MoO(2)(CMCAAP)(NCS)], [MoO(2)(CMCAAP)(NO(3))] and [MoO(2)(CMCAAP)(ClO(4))] (where CMCAAP = para-chlorometacresolazoantipyrine) have been synthesised and characterized by elemental analysis, molar conductance, magnetic susceptibility data, IR, UV-visible, ESR and (1)H NMR spectral studies. The thermal properties of the complex was investigated by thermogravimetric technique. The ligand and the complexes were screened for their possible antibacterial and antifungal activities. The complexes are found to be monomeric with distorted octahedral geometry. 
oxomolybdenum(V); dioxomolybdenum(VI); thermal studies