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HERO ID
1131360
Reference Type
Journal Article
Title
Pt-rich shell coated Ni nanoparticles as catalysts for methanol electro-oxidation in alkaline media
Author(s)
Fu, XZ; Liang, Y; Chen, SP; Lin, JD; Liao, DW
Year
2009
Is Peer Reviewed?
Yes
Journal
Catalysis Communications
ISSN:
1566-7367
Volume
10
Issue
14
Page Numbers
1893-1897
DOI
10.1016/j.catcom.2009.06.020
Web of Science Id
WOS:000269664200023
Abstract
The Pt-rich shell coated Ni nanoparticles in size of 8.9-12.1 nm were synthesized by chemical deposition via successive reduction of NiCl(2) and H(2)PtCl(6), respectively, in an ethylene glycol solution and characterized by TEM, XPS, ICP-AES, and XRD techniques. The electrochemical evaluation showed that as-prepared core-shell structural nanoparticles, as a catalyst for methanol electro-oxidation in alkaline media, not only exhibited better catalytic activity and resistance to carbonaceous intermediate poison than pure solid Pt nanoparticles but also decreased wastage of expensive Pt. (c) 2009 Elsevier B.V. All rights reserved.
Keywords
Pt coated Ni nanoparticles; Catalyst; Methanol oxidation; Alkaline media; Fuel cell
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•
Methanol (Non-Cancer)
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