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Citation
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HERO ID
1152538
Reference Type
Journal Article
Title
Anthracene-9-methanol - a novel fluorescent phototrigger for biomolecular caging
Author(s)
Singh, AK; Khade, PK
Year
2005
Is Peer Reviewed?
1
Journal
Tetrahedron Letters
ISSN:
0040-4039
EISSN:
1873-3581
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Location
OXFORD
Volume
46
Issue
33
Page Numbers
5563-5566
Language
English
DOI
10.1016/j.tetlet.2005.06.026
Web of Science Id
WOS:000230879300031
URL
https://linkinghub.elsevier.com/retrieve/pii/S0040403905012499
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Abstract
Photoexcitation of a solution of anthracene-9-methanol derived esters at similar to 386 nm in CH3CN/H2O (3:2 v/v) results in fluorescence emission in the 380-480 nm range, with quantum yields of fluorescence (Phi(f)) in the 0.01-0.09 range and releases of the carboxylic acids in good chemical yields (43-100%), with quantum yields of photoreaction (Phi(PR), i.e., the photodisappearance of the esters) in the 0.067-0.426 range. (c) 2005 Elsevier Ltd. All rights reserved.
Keywords
caging; anthracene-9-methanol; esters; photochemistry; phototrigger
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IRIS
•
Methanol (Non-Cancer)
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