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HERO ID
1170985
Reference Type
Journal Article
Title
Thermokinetic investigation of the reaction of acetyl chloride with different alcohol types - Part II
Author(s)
Willms, T; Anderson, HL; Heldt, K; Hinz, B
Year
2000
Is Peer Reviewed?
1
Journal
Thermochimica Acta
ISSN:
0040-6031
EISSN:
1872-762X
Volume
364
Issue
1-2
Page Numbers
47-58
Language
English
DOI
10.1016/S0040-6031(00)00705-X
Web of Science Id
WOS:000165783100005
Abstract
The ethanolysis of acetyl chloride has been compared to the methanolysis and the hydrolysis, as well as to the reaction with n-propanol, n-butanol and n-pentanol in acetone and in toluene, to reveal chain-length effects. Pentanol, heptanol and nonanol have been included as well in the investigation, but at lower concentrations. Structural influences on the alcoholysis of acetyl chloride have been studied with the isomeric C3 and C4-alcohols in acetone and in toluene. Furthermore, alcoholysis of acetyl chloride with some C7-alcohols and the reaction of benzoyl chloride with different types of alcohols have been investigated. © 2000 Published by Elsevier Science B.V.
Keywords
acetyl chloride; alcoholysis; kinetics; reaction enthalpies; butanol; propanol; benzyl alcohol; cyclohexyl methanol; n-heptanol
Tags
IRIS
•
Methanol (Non-Cancer)
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