Bicyclo[2.2.1]heptane-2-methanol transformations oil oxide catalysts
Gasanov, AG; Alieva, LI; Musaev, MR
| HERO ID | 1172450 |
|---|---|
| In Press | No |
| Year | 2000 |
| Title | Bicyclo[2.2.1]heptane-2-methanol transformations oil oxide catalysts |
| Authors | Gasanov, AG; Alieva, LI; Musaev, MR |
| Journal | Petroleum Chemistry |
| Volume | 40 |
| Issue | 4 |
| Page Numbers | 272-274 |
| Abstract | Bicyclo[2.2.1]heptane-2-methanol was synthesized by hydrogenation of bicyclo[2.2.1]hept-5-ene-2-methanol in a flow system on fixed-bed oxide catalysts, and its transformations were studied. Dehydration and isomerization of bicycloheptene structure with the double-bond migration were found to be the main transformation routes. Thus, 2-methylenebicyclo[2.2.1]heptane (norcamphene), the product of dehydration, was obtained with 47.2 or 61.0% yield in the presence of gamma-Al2O3 or aluminosilicate, respectively. The majority of norcamphene was isomerized to give bi- and monocyclic unsaturated hydrocarbons differing in position of the double bond. |
| Wosid | WOS:000088967100010 |
| Is Certified Translation | No |
| Dupe Override | No |
| Comments | Source: Web of Science 000088967100010 |
| Is Public | Yes |
| Is Qa | No |