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HERO ID
1182135
Reference Type
Journal Article
Title
Aniline methylation over AFI and AEL type molecular sieves
Author(s)
Elangovan, SP; Kannan, C; Arabindoo, B; Murugesan, V
Year
1998
Is Peer Reviewed?
1
Journal
Applied Catalysis A: General
ISSN:
0926-860X
EISSN:
1873-3875
Volume
174
Issue
1-2
Page Numbers
213-219
DOI
10.1016/s0926-860x(98)00189-6
Web of Science Id
WOS:000077348300023
URL
http://
://WOS:000077348300023
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Abstract
Alkylation of aniline with methanol over AlPO4-5, AlPO4-11, CoAPO-5, CoAPO-11, ZAPO-5 and ZAPO-11 in the vapour phase has been studied. The products formed are N-methylaniline (N-MA), N,N-dimethylaniline (NN-DMA) and N-methyltoluidine (N-MT). The product distribution is influenced by temperature, (WHSV)-1 and ratio of aniline and methanol. Acidity of the catalysts plays an important role in the methylation of aniline. A direct relationship between total acidity and conversion was observed. © 1998 Elsevier Science B.V. All rights reserved.
Keywords
aniline; methylation; aluminophosphate; molecular sieves
Tags
IRIS
•
Methanol (Non-Cancer)
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