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HERO ID
1188331
Reference Type
Journal Article
Title
Association model of fluids. Phase equilibria and excess enthalpies in mixtures containing alcohol and acetonitrile
Author(s)
Nagata, I; Tamura, K; Gotoh, K
Year
1997
Is Peer Reviewed?
1
Journal
Zeitschrift fur Physikalische Chemie
ISSN:
0942-9352
Volume
199
Page Numbers
1-23
DOI
10.1524/zpch.1997.199.Part_1.001
Web of Science Id
WOS:A1997WP81300001
Abstract
The binary vapor-liquid, liquid-liquid equilibria and excess molar enthalpies of mixtures including alcohol and acetonitrile are correlated well with a new association model whose equilibrium constants are defined in terms of the modified segment fractions of chemical species. The model shows a good performance in predicting the ternary phase equilibria and excess molar enthalpies for mixtures containing alcohol, acetonitrile, and benzene or chlorobenzene or toluene from only binary parameters.
Keywords
association model; vapor-liquid equilibria; liquid-liquid equilibria; excess enthalpy; mixture
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Methanol (Non-Cancer)
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