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Citation
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HERO ID
1191523
Reference Type
Journal Article
Title
Polymer-supported tripyridylmethane derivatives: Lewis acid catalyzed ring opening of styrene oxide
Author(s)
Levacher, V; Adolfsson, H; Moberg, C
Year
1996
Is Peer Reviewed?
Yes
Journal
Acta Chemica Scandinavica
ISSN:
0904-213X
EISSN:
1902-3103
Publisher
MUNKSGAARD INT PUBL LTD
Location
COPENHAGEN
Volume
50
Issue
5
Page Numbers
454-457
DOI
10.3891/acta.chem.scand.50-0454
Web of Science Id
WOS:A1996UM66700012
Abstract
Tri(2-pyridyl)methanol was allowed to react with 1% crosslinked gel-type chloromethylated polystyrene in the presence of a base to yield a polymeric tridentate ligand. A macroporous chloromethylated polymer was unreactive under the same conditions. In this case, grafting was accomplished after reaction of tri(2-pyridyl)methanol with a spacer containing a phenolic group, which after deprotonation readily reacted with the polymer. An Fe(III) complex of the polymeric ligand was used as a Lewis acid in the methanolysis of styrene oxide.
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IRIS
•
Methanol (Non-Cancer)
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