Journal Article
ADDITION-COMPOUNDS OF NUCLEOPHILES AND 3-ETHYLTHIO-6-OXO-6H-1,2-DITHIOLO[4,3-C]1,2-DITHIOLIUM TETRAFLUOROBORATE - SYNTHESIS OF 3H,6H-1,2-DITHIOLO[4,3-C]1,2-DITHIOLE-3-ONE-6-THIONE
Kordts, B; Richter, AM; Fanghanel, E
Monatshefte für Chemie / Chemical Monthly
ISSN: 0026-9247
EISSN: 1434-4475
A smooth method of synthesizing 3 H, 6 H-1,2-dithiolo[4,3-c]1,2-dithiole-3,6-dithione (3), and also its partial desulfuration to yield 3 H, 6 H-1,2-dithiolo[4,3-c]1,2-dithiole-3-one-6-thione (4) is presented. The ethylation product 5 of the monothione 4 reacts with various nucleophilic reagents to form remarkably stable adducts. The adducts of 5 with methanol, tert-butyl mercaptan, and with aniline could be isolated and characterized by their1H-NMR spectra. © 1991 Springer-Verlag.
3H,6H-1,2-DITHIOLO[4,3-C]1,2-DITHIOLE-3,6-DITHIONE,; SYNTHESIS AND PARTIAL DESULFURATION OF; 3H,6H-1,2-DITHIOLO[4,3-C]1,2-DITHIOLE-3-ONE-6-THIONE,; SYNTHESIS AND ALKYLATION OF; 3-ETHYLTHIO-6-OXO-6H-1,2-DITHIOLO[4,3-C]1,2-DITHIOLIUM; TETRAFLUOROBORATE, SYNTHESIS AND FORMATION OF ADDUCTS WITH; NUCLEOPHILES OF