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1198391 
Journal Article 
STEREOSPECIFIC RING-OPENING AT THE BENZYLIC CARBON OF PHENYLOXIRANE DERIVATIVES BY ALCOHOLS 
Niibo, Y; Nakata, T; Otera, J; Nozaki, H 
1991 
Synlett
ISSN: 0936-5214
EISSN: 1437-2096 
Georg Thieme Verlag 
1991 
97-98 
English 
Optically pure phenyl-substituted oxiranes underwent stereospecific ring opening at the benzylic position by benzyl alcohol and methanol with complete inversion under the catalysis of organotin phosphate condensates. With recourse to this reaction, a novel procedure for (S)-phenyloxirane was achieved from the readily available R counterpart via (S)-2-benzyloxy-2-phenylethanol. © 1991 Georg Thieme Verlag. All rights reserved. 
IRIS
• Methanol (Non-Cancer)
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