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1206393 
Journal Article 
KINETICS OF THE CATALYTIC HYDROCHLORINATION OF METHANOL TO METHYL-CHLORIDE 
Becerra, AM; Luna, AEC; Ardissone, DE; Ponzi, MI 
1992 
Yes 
Industrial and Engineering Chemistry Research
ISSN: 0888-5885
EISSN: 1520-5045 
31 
4 
1040-1045 
WOS:A1992HN89800011 
The intrinsic kinetics of the catalytic hydrochlorination of methanol to methyl chloride on gamma-Al2O3 was determined from experiments in a tubular reactor in the temperature range of 513-593 K and at atmospheric pressure, after a catalyst screening and a study of operative conditions. A large number of detailed reaction mechanisms was considered. A strategy of model discrimination and parameter estimation led to a Hougen-Watson type model with statistically significant and thermodynamically consistent parameters. 
IRIS
• Methanol (Non-Cancer)
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