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1343861 
Journal Article 
SYNTHESIS AND PROPERTIES OF S-(TRIFLUOROMETHYL)POLYSULFANEMONOSULFONATES CF(3)S(X)SO(2)M [X=1, M=OH, NH4O, 1/2 HGO2, (CH3)(3)SIO, (CH3)(2)N, NH2 X=2, M=NH4O] 
Brosius, A; Haas, A; Pryka, M 
1994 
1 
Chemische Berichte
ISSN: 0009-2940 
127 
3 
457-463 
WOS:A1994NC94600002 
Hydrolysis of CF3SNSO with 2 equiv. of H2O provides [NH4]
[CF3SSO3] (1), which on treatment with chlorine gives CF3SCl and [NH4][ClSO3]. Trifluoromethyl
thiosulfates are synthesized from Hg(SCF3)(2) and ClSO(2)M [M = NH4O, (CH3)(3)SiO (2), (CH3)(2)N
(3), NH2 (4)]. Insertion of SO3 into Hg(SCF3)(2) provides Hg[CF3SSO2O](2) (6). Similarly, S-
(trifluoromethyl)thiosulfuric acid (5) is obtained from CF3SH and SO3. New preparations for
CF3SxNSO (x=1, 2) are described. 
(TRIFLUOROMETHYL)SULFANE- AND -DISULFANESULFONIC ACIDS; MERCURY COMPOUNDS; (TRIFLUOROMETHYL) SULFANYL-, -DISULFANYL, AND -SULFINYLIMINE; ARSENIC COMPOUNDS