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Citation
Tags
HERO ID
1423838
Reference Type
Journal Article
Title
The first uranyl-methine carbon bond; a complex with out-of-plane uranyl equatorial coordination
Author(s)
Sarsfield, MJ; Helliwell, M; Collison, D
Year
2002
Is Peer Reviewed?
Yes
Journal
Chemical Communications
ISSN:
1359-7345
EISSN:
1364-548X
Issue
19
Page Numbers
2264-2265
Language
English
PMID
12398008
Abstract
Treatment of [UO2Cl2(thf)3] in thf with one equivalent of [Na(CH(Ph2P = NSiMe3)2)] yields an unusual uranyl chloro-bridged dimer containing a uranium(VI)-carbon bond as part of a tridentate bis(iminophosphorano)methanide chelate complex. The methine carbon is displaced significantly from the uranyl equatorial plane.
Tags
IRIS
•
Uranium
Pubmed
Merged reference set
Secondary Refinement
Retained for manual screening
Excluded:
Not chemical specific
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