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HERO ID
1576628
Reference Type
Journal Article
Title
KINETICS AND MECHANISM OF OXIDATION OF D-GLUCOPYRANOSE 6-PHOSPHATE AND D-RIBOFURANOSE 5-PHOSPHATE BY CHROMIUM(VI) IN PERCHLORIC-ACID MEDIA
Author(s)
Sengupta, KK; Sengupta, S; Mandal, SK; Basu, SN
Year
1985
Is Peer Reviewed?
Yes
Journal
Carbohydrate Research
ISSN:
0008-6215
EISSN:
1873-426X
Volume
139
Issue
JUN
Page Numbers
185-190
Language
English
DOI
10.1016/0008-6215(85)90018-7
Web of Science Id
WOS:A1985ALS7000018
Abstract
The kinetics of oxidation of d-glucopyranose 6-phosphate and d-ribofuranose 5-phosphate by chromium(VI) in perchloric acid media have been studied by u.v. spectroscopy. Each reaction is first order with respect to [chromium(VI)] and [substrate]. The reactions are acid-catalysed and accelerated by the addition of sodium perchlorate. The mechanism of the reactions is discussed. © 1985.
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IRIS
•
Chromium VI
Considered
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Other Not Pertinent
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