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HERO ID
2596781
Reference Type
Journal Article
Title
Characteristics of organic and elemental carbon in PM2.5 samples in Shanghai, China
Author(s)
Feng, Y; Chen, Y; Guo, Hui; Zhi, G; Xiong, S; Li, Jun; Sheng, G; Fu, J
Year
2009
Is Peer Reviewed?
Yes
Journal
Atmospheric Research
ISSN:
0169-8095
EISSN:
1873-2895
Volume
92
Issue
4
Page Numbers
434-442
DOI
10.1016/j.atmosres.2009.01.003
Web of Science Id
WOS:000266530400007
Abstract
Shanghai is the largest industrial and commercial city in China, and its air quality has been deteriorating for several decades. However, there are scarce researches on the level and seasonal variation of fine particle (PM2.5) as well as the carbonaceous fractions when compared with other cities in China and around the world. In the present paper, abundance and seasonal characteristics of PM2.5, organic carbon (OC) and elemental carbon (EC) were studied at urban and suburban sites in Shanghai during four season-representative months in 2005-2006 year. PM2.5 samples were collected with high-vol samplers and analyzed for OC and EC using thermal-optical transmittance (TOT) protocol. Results showed that the annual average PM2.5 concentrations were 90.3-95.5 mu g/m(3) at both sites, while OC and EC were 14.7-17.4 mu g/m(3) and 2.8-3.0 mu g/m(3), respectively, with the OC/EC ratios of 5.0-5.6. The carbonaceous levels ranked by the order of Beijing > Guangzhou > Shanghai > Hong Kong. The carbonaceous aerosol accounted for similar to 30% of the PM2.5 mass. On seasonal average, the highest OC and EC levels occurred during fall, and they were higher than the values in summer by a factor of 2. Strong correlations (r = 0.79-0.93) between OC and EC were found in the four seasons. Average level of secondary organic carbon (SOC) was 5.7-7.2 mu g/m(3), accounting for similar to 30% of the total OC. Strong seasonal variation was observed for SOC with the highest value during fall, which was about two times the annual average. (C) 2009 Elsevier B.V. All rights reserved.
Keywords
Organic carbon; Elemental carbon; Fine particle (PM2.5); Seasonal variation; Shanghai
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