US EPA

2645665 

Journal Article 

A global model of mass independent mercury stable isotope fractionation 

Sonke, JE 

2011 

No 

Geochimica et Cosmochimica Acta
ISSN: 0016-7037 

Elsevier 

OXFORD 

75 

16 

4577-4590 

English 

10.1016/j.gca.2011.05.027 

WOS:000293015500013 

Mass independent fractionation (MIF) of stable isotopes associated with terrestrial geochemical processes was first observed in the 1980s for oxygen and in the 1990s for sulfur isotopes. Recently mercury (Hg) was added to this shortlist when positive odd Hg isotope anomalies were observed in biological tissues. Experimental work identified photoreduction of aquatic inorganic divalent Hg(II) and photodegradation of monomethylmercury species as plausible MIF inducing reactions. Observations of continental receptors of atmospheric Hg deposition such as peat, lichens, soils and, indirectly, coal have shown predominantly negative MIF. This has led to the suggestion that atmospheric Hg has negative MIF signatures and that these are the compliment of positive Hg MIF in the aquatic environment. Recent observations on atmospheric vapor phase Hg(0) and Hg(II) in wet precipitation reveal zero and positive Hg MIF respectively and are in contradiction with a simple aquatic Hg(II) photoreduction scenario as the origin for global Hg MIF observations.



This study presents a synthesis of all terrestrial Hg MIF observations, and these are integrated in a one-dimensional coupled continent-ocean-atmosphere model of the global Hg cycle. The model illustrates how Hg MIF signatures propagate through the various Earth surface reservoirs. The scenario in which marine photoreduction is the main MIF inducing process results in negative atmospheric Delta(199)Hg and positive ocean Delta(199)Hg of -0.5 parts per thousand and +0.25 parts per thousand, yet does not explain atmospheric Hg(0) and Hg(II) wet precipitation observations. Alternative model scenarios that presume in-cloud aerosol Hg(II) photoreduction and continental Hg(II) photoreduction at soil, snow and vegetation surfaces to display MIF are necessary to explain the ensemble of natural observations. The model based approach is a first step in understanding Hg MIF at a global scale and the eventual incorporation of Hg stable isotope information in detailed global mercury chemistry and transport models. (C) 2011 Elsevier Ltd. All rights reserved. 

GEOCHIMICA ET COSMOCHIMICA ACTA