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3115335 
Journal Article 
Promoting role of bismuth on carbon nanotube supported platinum catalysts in aqueous phase aerobic oxidation of benzyl alcohol 
Zhou, C; Guo, Z; Dai, Y; Jia, X; Yu, Hao; Yang, Y 
2016 
Yes 
Applied Catalysis B: Environmental
ISSN: 0926-3373 
Elsevier 
181 
118-126 
English 
WOS:000364256000013 
PtBi/CNT catalyst was synthesized by a one-step polyol reduction method assisted by microwave radiation, and its catalytic performance was investigated in aerobic oxidation of benzyl alcohol in the aqueous phase. Pt and BiOx species uniformly dispersed on the CNT surfaces and strong synergic interaction between them occurred, which confirmed by the comprehensive analysis of TEM, XRD, XPS and electrochemical characterizations. Further investigations revealed that the synergic effect effectively promoted the activation of both molecular oxygen and benzyl alcohol substrate; also protected Pt active sites from over-oxidization. The advantage of such synergic effect was reflected in the increased yield for the desired product benzaldehyde: PtBi/CNT catalyst exhibited about 3.5 times higher yield toward benzaldehyde compared to Pt/CNT catalyst. Furthermore, owing to the positive effect of Bi avoiding Pt from oxidizing, the deactivation of PtBi/CNT (with 2% selectivity and 9% conversion decrease) is much slower than that of Pt/CNT (with 8% selectivity and 39% conversion decrease) after six reaction cycles. PtBi/CNT catalyst was proved as a remarkably effective catalyst with high stability for the aerobic oxidation of benzyl alcohol. (C) 2015 Elsevier B.V. All rights reserved. 
Platinum; Bismuth oxides; Benzyl alcohol; Aerobic oxidation; Synergic effect 
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