A novel open-framework copper borophosphate containing 1-D borophosphate anion with 10-MR windows and 12-MR channels | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

3727359

Reference Type

Journal Article

Title

A novel open-framework copper borophosphate containing 1-D borophosphate anion with 10-MR windows and 12-MR channels

Author(s)

Feng, Y; Li, M; Fan, H; Huang, Q; Qiu, D; Shi, H

Year

2015

Is Peer Reviewed?

Yes

Journal

Dalton Transactions (Online)
ISSN: 1477-9234

Volume

Issue

Page Numbers

894-897

Language

English

PMID

25437261

DOI

10.1039/c4dt02840f

Web of Science Id

WOS:000346413200004

Abstract

A novel open-framework copper borophosphate, Na5KCu3[B9P6O33(OH)3]·H2O (), has been synthesised by a boric acid flux method. Its structure can be viewed as a 3-D open framework constructed by the connection of Cu(II)O6 octahedra and 1-D (4,4)-connected borophosphate anionic structures composed of trigonal-planar BO2(OH) groups, tetrahedral BO4 and PO4 groups. The compound not only features a novel borophosphate anionic partial structure containing 1-D 12-MR channels, but also exhibits ferromagnetic interactions and high catalytic activity for the oxidative degradation of chitosan.