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HERO ID
4188090
Reference Type
Journal Article
Title
Synthesis of Nano-Structured HgS by Sol-Gel
Author(s)
Kharghanian, L; Moghimi, Ali
Year
2013
Is Peer Reviewed?
Yes
Journal
Asian Journal of Chemistry
ISSN:
0970-7077
EISSN:
0975-427X
Volume
25
Issue
11
Page Numbers
5904-5906
DOI
10.14233/ajchem.2013.13240
Web of Science Id
WOS:000325089600004
Abstract
The main focus is laid on the sol-gel synthesis is opening a wide window toward nano-scopic metal sulfides with remarkable properties different from that of crystalline metal sulfides. Nanocomposites HgS/SiO2 has been prepared by the sol-gel method starting from methyltriethoxysilane (MTEOS) precursors as the SiO2 sources and mercaptopropyltrimethoxysilane (MPTMS) as the capping agent. The average diameter of HgS particles in the nano-composite materials can be controlled by the cadmium concentration and thermally treatment. The dried gel was treated at increasing temperatures, The crystallinity, shape and size of the metal sulfide nanocrystals were investigated by X-ray diffraction and transmission electron microscopy. The result indicates that the formation and the stability of the mercury sulfide phases are strongly affected by the precursors used as the mercury sources.
Keywords
Nano-structured Hg sulfides; Mercury sulfide in silica matrix; Sol-gel; Properties
Tags
•
Inorganic Mercury Salts (2)
Mercuric Sulfide
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