US EPA

4188860 

Journal Article 

Improvement of the stability of Hg/AC catalysts by CsCl for the high-temperature hydrochlorination of acetylene 

Xu, XL; Zhao, Jia; Lu, CS; Zhang, TT; Di, XXia; Gu, SC; Li, XN 

2016 

1 

Chinese Chemical Letters
ISSN: 1001-8417
EISSN: 1878-5964 

27 

6 

822-826 

10.1016/j.cclet.2016.01.014 

WOS:000379271500004 

Activated carbon-supported mercuric chloride (HgCl2) is used as an industrial catalyst for acetylene hydrochlorination. However, the characteristic of easy sublimation of HgCl2 leads to the deactivation of the catalyst. Here, we showed that the thermal stability of the Hg/AC catalyst can be evidently improved when CsCl is added into the Hg/AC catalyst. Compared with the pure Hg/AC catalyst, the sublimation rate of HgCl2 from the Hg-Cs/AC catalyst decreased significantly and the Hg-Cs/AC catalyst showed better catalytic activity and stability in the reaction. This promoting effect is related to the existence of cesium mercuric chlorides (CsxHgyClx+2y,) highlighted by XRD, HR-TEM and EDX analyses. Thus, reacting HgCl2 with alkali chlorides to form alkali-mercuric chlorides may be a key to design highly efficient and thermally stable mercuric chloride catalyst for hydrochlorination reactions. (C) 2016 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved. 

Cesium chloride; Mercuric chloride; Sublimation; Hydrochlorination of acetylene; Cesium-mercuric chlorides