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4191175 
Journal Article 
Conversion constants for redox potentials measured versus different reference electrodes in acetonitrile solutions at 25 degrees C 
Pavlishchuk, VV; Addison, AW 
2000 
1 
Inorganica Chimica Acta
ISSN: 0020-1693
EISSN: 1873-3255 
298 
1 
97-102 
WOS:000085017600016 
Caution should be exercised when one is comparing the redox potentials of complexes measured in CH3CN solutions Versus different reference electrodes. A critical review of conversion constants amongst various reference electrodes reported in the literature reveals that in most cases the comparisons of redox potential values are far from accurate. From measurements of relationships amongst various common reference electrodes in CH3CN solutions, conversion constants for redox potentials measured Versus different reference electrodes in acetonitrile solutions at 25 degrees C are proposed, along with a convention for reporting redox potential values. (C) 2000 Elsevier Science S.A. All rights reserved. 
electrochemistry; redox potentials; conversion constants; voltammetry; ferrocene; acetonitrile; saturated calomel electrode 
• Inorganic Mercury Salts (2)
     Mercurous Chloride
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