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Citation
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HERO ID
4272320
Reference Type
Journal Article
Title
Non-oxidative Coupling of Methane to Ethylene Using Mo2C/[B]ZSM-5
Author(s)
Sheng, H; Schreiner, EP; Zheng, W; Lobo, RF
Year
2018
Is Peer Reviewed?
1
Journal
ChemPhysChem
ISSN:
1439-4235
EISSN:
1439-7641
Volume
19
Issue
4
Page Numbers
504-511
Language
English
PMID
29045043
DOI
10.1002/cphc.201701001
Web of Science Id
WOS:000425458200019
URL
http://
://WOS:000425458200019
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Abstract
Methane non-oxidative coupling to ethylene was investigated on Mo2C/[B]ZSM-5 catalyst at 923 K and atmospheric pressure. In contrast to Mo2C/[Al]ZSM-5 catalysts for methane aromatization, this material exhibits very high ethylene selectivity (>90 %) and low aromatics (benzene and naphthalene) selectivity. The much weaker Brønsted acidity of [B]ZSM-5 leads to a slow rate of ethylene oligomerization. The stability of the catalyst is greatly enhanced with 93 % of the initial reaction rate remaining after 18 h of time on stream. In-situ UV/VIS spectra indicate that prior to carburization, mono/binuclear Mo oxides are initially well dispersed onto the zeolite support. Mo carbides clusters, formed during carburization with methane, appear similar to clusters formed in [Al]ZSM-5, as indicated by the X-ray Absorption Spectroscopy (XAS) data.
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Molybdenum
Litsearch 2018
Pubmed
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Naphthalene
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PubMed
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Data set for title/abstract screening
Excluded - PECO criteria not met (TIAB)
Feb 2019 Update
PubMed
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Naphthalene (2021 Evidence mapping publication)
Database Searches
PubMed
Combined data set
Data set for title/abstract screening
Excluded – PECO criteria not met
Feb 2019 Update
PubMed
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