US EPA

517846 

Journal Article 

Ion microprobe U-Pb dating of a dinosaur tooth 

Sano, Y; Terada, K; Ly, CV; Park, EJ 

2006 

1 

Geochemical Journal
ISSN: 0016-7002
EISSN: 1880-5973 

40 

2 

171-179 

English 

WOS:000236101300005 

Ion microprobe U-Pb dating of apatite is applied to a fossil tooth of a Allosaurid derived from the Hasandong Formation in the Gyeongsang basin, southeastern Korea. Twelve spots on a single fragment of the fossil dentine yield a Tera-Wasserburg concordia intercept age of 115 +/- 10 Ma (2 sigma, MSWD = 0.59) on a (238)u/Pb-206-Pb-207/(PbPb)-Pb-206-Pb-204/Pb-206 diagram. The age provides a constraint on the depositional age of the fossil in its host Hasandong Formation as Early Aptian. The success of the ion microprobe dating depends on the heterogeneities of diagenetically incorporated U and Pb at the few hundred pm scale, the consequent variations in Pb isotopic compositions due to radioactive decay and the closed-system behavior of U and Pb. There are at least three end-members to explain the variations of minor chemical components such as FeO, SiO,, and Al2O3, and trace elements such as Th, U and rare earth elements (REE) in the sample by a simple mixing model. They are (1) very low minor and REE, very high common Pb with variable U abundances, (2) low common Pb, high minor, REE, and U abundances, and (3) low minor, common Pb, and U with intermediate REE abundances, even though groups (2) and (3) may consist of a larger group. Various contributions of the three (and/or two) end-members during diagenetic prosesses may cause the elemental fractionation of U and Pb in a fossil tooth. 

fossil tooth; dinosaur; U-Pb dating; rare earth elements; diagenetic; process; rare-earth-elements; lead diffusion; fossil bones; apatite; diagenesis; carbonate; exposure; uranium; phosphorites; evolution