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Citation
Tags
HERO ID
5343831
Reference Type
Journal Article
Title
Kinetics of chlorate formation during ozonation of aqueous chloride solutions
Author(s)
Levanov, AV; Isaikina, OY; Gasanova, RB; Uzhel, AS; Lunin, VV
Year
2019
Is Peer Reviewed?
Yes
Journal
Chemosphere
ISSN:
0045-6535
EISSN:
1879-1298
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Location
OXFORD
Volume
229
Page Numbers
68-76
Language
English
PMID
31075704
DOI
10.1016/j.chemosphere.2019.04.105
Web of Science Id
WOS:000471087400009
URL
https://linkinghub.elsevier.com/retrieve/pii/S0045653519307581
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Abstract
Chlorate ion ClO3- is formed as a result of the complex chemical interaction of ozone with chloride ion in aqueous solution. In neutral and basic solutions, chlorate is the main product. In acid solutions, the main product is molecular chlorine Cl2, and the yield of chlorate is 50-100 times lower. Dependencies have been studied of chlorate formation rate on significant experimental factors: concentrations of initial substances, ozone and chloride ion, acidity (pH), ionic strength and temperature of the reaction solution. The kinetic laws of chlorate generation have been established, and the expressions are given for rate constants of chlorate formation as functions of temperature and ionic strength. When tert-butanol is added to the reaction system, the formation of chlorate ceases, which is an evidence of the crucial role of free radical reactions in this process.
Tags
IRIS
•
tert-Butanol
Excluded/ Not on Topic
Chemical Analysis/Fuel Chemistry
LitSearch: Jan 2017 - July 2019
PubMed
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