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Citation
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HERO ID
6333747
Reference Type
Journal Article
Title
Synthesis of polymer-silica hybrid-supported catalysts for solvent-free oxidation of ethylbenzene with TBHP
Author(s)
Chaudhary, V; Sharma, S
Year
2020
Is Peer Reviewed?
Yes
Journal
Asia-Pacific Journal of Chemical Engineering
ISSN:
1932-2135
EISSN:
1932-2143
Volume
15
Issue
3
Page Numbers
e2441
Language
English
DOI
10.1002/apj.2441
Web of Science Id
WOS:000517791100001
Abstract
Polymer-silica hybrid support was synthesized, and Cu (II), Co (II), Mn (II), and Ni (II) metals were loaded over hybrid support by incipient impregnation method. Oxidation of ethylbenzene was performed for catalytic evaluation of catalysts at different reaction conditions, that is, the mole ratio of ethylbenzene to TBHP and reaction temperature. The main reaction product was acetophenone along with benzaldehyde as the minor product. The highest ethylbenzene conversion (96.5%) was attained at a 1:3 mole ratio of ethylbenzene to TBHP and temperature at 100 degrees C. Activation energy and reusability of the catalysts were also determined, and results showed that they can be easily reused three times without much loss in their structural and catalytic properties.
Keywords
catalysis; catalytic oxidation; polymers; regeneration
Tags
•
Cobalt
LitSearch Update: January 2019 - December 2021
WoS
•
Ethylbenzene
Litsearch Update April 2020
WOS
Litsearch November 2020
WoS
2020 Update Screening HERO tags
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