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6667835 
Journal Article 
Homogeneous catalytic oxidation of alkenes employing mononuclear vanadium complex with hydrogen peroxide 
Maurya, A; , 
2020 
Yes 
Journal of the Iranian Chemical Society
ISSN: 1735-207X
EISSN: 1735-2428 
SPRINGER 
NEW YORK 
17 
12 
3261-3269 
Homogeneous liquid-phase oxidation of alkenes (allylbenzene, cis-cyclooctene, 4-chlorostyrene, styrene, 2-norbornene, 1-methyl cyclohexene, indene, lemonine, and 1-hexene) were catalyzed by using vanadium complex [VO(hyap)(acac)(2)] in existence of H2O2. The complex [VO(hyap)(acac)(2)] was formed as a crystal by the reaction of [VO(acac)(2)] and 2-hydroxy-acetophenone (hyap) in the presence of methanol by refluxing the reaction mixture. Various analytical and spectroscopic techniques, namely FTIR, ESI-MS, UV-Vis, single-crystal XRD, and EPR, were used to analyze and optimize the structure of the complexes.[GRAPHICS]. 
Vanadium(IV) complex; Homogeneous catalysis; Alkenes oxidation