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Citation
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HERO ID
6667835
Reference Type
Journal Article
Title
Homogeneous catalytic oxidation of alkenes employing mononuclear vanadium complex with hydrogen peroxide
Author(s)
Maurya, A; ,
Year
2020
Is Peer Reviewed?
Yes
Journal
Journal of the Iranian Chemical Society
ISSN:
1735-207X
EISSN:
1735-2428
Publisher
SPRINGER
Location
NEW YORK
Volume
17
Issue
12
Page Numbers
3261-3269
DOI
10.1007/s13738-020-01988-x
Web of Science Id
WOS:000546833000001
Abstract
Homogeneous liquid-phase oxidation of alkenes (allylbenzene, cis-cyclooctene, 4-chlorostyrene, styrene, 2-norbornene, 1-methyl cyclohexene, indene, lemonine, and 1-hexene) were catalyzed by using vanadium complex [VO(hyap)(acac)(2)] in existence of H2O2. The complex [VO(hyap)(acac)(2)] was formed as a crystal by the reaction of [VO(acac)(2)] and 2-hydroxy-acetophenone (hyap) in the presence of methanol by refluxing the reaction mixture. Various analytical and spectroscopic techniques, namely FTIR, ESI-MS, UV-Vis, single-crystal XRD, and EPR, were used to analyze and optimize the structure of the complexes.[GRAPHICS].
Keywords
Vanadium(IV) complex; Homogeneous catalysis; Alkenes oxidation
Tags
•
Vanadium Compounds - Oral
Literature Search: Mar 2019 - Mar 2020
WoS
Combined data set
Excluded by SWIFT Review screen
•
Vanadium Inhalation
Literature Search: Mar 2019 – Mar 2020
WoS
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