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Citation
Tags
HERO ID
7308220
Reference Type
Journal Article
Title
A Crystalline, 2D Polyarylimide Cathode for Ultrastable and Ultrafast Li Storage
Author(s)
Wang, G; Chandrasekhar, N; Biswal, BP; Becker, D; Paasch, S; Brunner, E; Addicoat, M; Yu, M; Berger, R; Feng, X
Year
2019
Is Peer Reviewed?
Yes
Journal
Advanced Materials
ISSN:
0935-9648
EISSN:
1521-4095
Volume
31
Issue
28
Page Numbers
e1901478
Language
English
PMID
31099072
DOI
10.1002/adma.201901478
Web of Science Id
WOS:000477972300021
URL
http://
://WOS:000477972300021
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Abstract
Organic electrode materials are of long-standing interest for next-generation sustainable lithium-ion batteries (LIBs). As a promising cathode candidate, imide compounds have attracted extensive attention due to their low cost, high theoretical capacity, high working voltage, and fast redox reaction. However, the redox active site utilization of imide electrodes remains challenging for them to fulfill their potential applications. Herein, the synthesis of a highly stable, crystalline 2D polyarylimide (2D-PAI) integrated with carbon nanotube (CNT) is demonstrated for the use as cathode material in LIBs. The synthesized polyarylimide hybrid (2D-PAI@CNT) is featured with abundant π-conjugated redox-active naphthalene diimide units, a robust cyclic imide linkage, high surface area, and well-defined accessible pores, which render the efficient utilization of redox active sites (82.9%), excellent structural stability, and fast ion diffusion. As a consequence, high rate capability and ultrastable cycle stability (100% capacity retention after 8000 cycles) are achieved in the 2D-PAI@CNT cathode, which far exceeds the state-of-the-art polyimide electrodes. This work may inspire the development of novel organic electrodes for sustainable and durable rechargeable batteries.
Tags
IRIS
•
Naphthalene
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PubMed
Combined data set
Data set for title/abstract screening
Excluded - PECO criteria not met (TIAB)
January 2021 Update
PubMed
Other
•
Naphthalene (2021 Evidence mapping publication)
Database Searches
PubMed
Combined data set
Data set for title/abstract screening
Excluded – PECO criteria not met
January 2021 Update
PubMed
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