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HERO ID
738295
Reference Type
Journal Article
Title
Concise synthesis and crystal structure of [12]cycloparaphenylene
Author(s)
Segawa, Y; Miyamoto, S; Omachi, H; Matsuura, S; Šenel, P; Sasamori, T; Tokitoh, N; Itami, K
Year
2011
Is Peer Reviewed?
Yes
Journal
Angewandte Chemie (International Edition)
ISSN:
1433-7851
EISSN:
1521-3773
Volume
50
Issue
14
Page Numbers
3244-3248
Language
English
PMID
21370367
DOI
10.1002/anie.201007232
Abstract
Crystal clear: The title macrocycle was constructed by a nickel-mediated shotgun macrocyclization. The X-ray crystallographic structure of [12]CPP revealed a circular structure incorporating two cyclohexane molecules within the ring. The [12]CPP molecules were also found to crystallize into tubular and herringbone structures. Copyright 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Keywords
cycloparaphenylenes; macrocycles; nanotubes; x-ray crystal structures
Tags
Other
•
Nanoscale Carbon
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