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Citation
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HERO ID
738941
Reference Type
Journal Article
Title
Bio-inspired Heterostructured Bead-on-String Fibers That Respond to Environmental Wetting
Author(s)
Tian, X; Bai, H; Zheng, Y; Jiang, L
Year
2011
Is Peer Reviewed?
Yes
Journal
Advanced Functional Materials
ISSN:
1616-301X
EISSN:
1616-3028
Volume
21
Issue
8
Page Numbers
1398-1402
DOI
10.1002/adfm.201002061
Web of Science Id
WOS:000289638500007
URL
http://doi.wiley.com/10.1002/adfm.201002061
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Abstract
Inspired by the geometric structure of ecribellate spider capture silk and its spinning characteristics, we propose a one-step electrohydrodynamic method to fabricate bead-on-string heterostructured fibers (BSHFs). By combining electrospinning and electrospraying strategies using a sprayable outer fluid with low viscosity and a spinnable inner fluid with high viscosity in a coaxial jetting process, hydrophilic poly(ethylene glycol) beads are successfully imprinted on a hydrophobic polystyrene string. It is demonstrated that the BSHFs are capable of intelligently responding to environmental change. With a change in relative humidity, the fibers show a segmented swelling and shrinking behavior in the "bead" parts whereas the "string" parts remain the same. The elastic BSHFs with alternating hydrophilic and hydrophobic surface characteristics represent a type of mesoscale analogues that block copolymers and may bring about new properties and applications. Moreover, the combined electrohydrodynamic approach developed herein should open new routes to multifunctional one-dimensional heterostructured materials.
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Nanoscale Carbon
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