Synthesis and structure of the calixarene-like phosph(III)azane macrocycle [{P(mu-N(t)Bu)}2{1,5-(NH)2C10H6}]3 | Health & Environmental Research Online (HERO)

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HERO ID

1468698

Reference Type

Journal Article

Title

Synthesis and structure of the calixarene-like phosph(III)azane macrocycle [{P(mu-N(t)Bu)}2{1,5-(NH)2C10H6}]3

Author(s)

Dodds, F; García, F; Kowenicki, RA; Mcpartlin, M; Steiner, A; Wright, DS

Year

2005

Is Peer Reviewed?

Yes

Journal

Chemical Communications
ISSN: 1359-7345
EISSN: 1364-548X

Issue

Page Numbers

3733-3735

Language

English

PMID

16027927

DOI

10.1039/b504686f

Web of Science Id

WOS:000230596700031

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-23644436812&doi=10.1039%2fb504686f&partnerID=40&md5=3071a00cd627d2597d209faff04f8352
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Abstract

The reaction of [ClP(mu-NtBu)]2 with 1,5-diamino-naphthalene [1,5-(NH2)2C10H6] in Et3N-thf gives the trimeric macrocycle [{P(mu-NtBu)}2{1,5-(NH)2C10H6}]3(1); the X-ray structure of the toluene solvate 1.3toluene reveals a cone-shaped (calixarene-like) arrangement in which toluene guest molecules are trapped within the cavity.

Keywords

article; X-ray diffraction; chemical reactions; toluene