Jump to main content
US EPA
United States Environmental Protection Agency
Search
Search
Main menu
Environmental Topics
Laws & Regulations
About EPA
Health & Environmental Research Online (HERO)
Contact Us
Print
Feedback
Export to File
Search:
This record has one attached file:
Add More Files
Attach File(s):
Display Name for File*:
Save
Citation
Tags
HERO ID
3860583
Reference Type
Journal Article
Title
The mass spectra of 4-aminophenanthrene and its trifluoroacetic anhydride and perfluoropropionic anhydride derivatives
Author(s)
Campbell, JA; Chess, EK; Connolly, MJ
Year
1990
Is Peer Reviewed?
Yes
Journal
Biomedical and Environmental Mass Spectrometry
ISSN:
0887-6134
Volume
19
Issue
10
Page Numbers
613-618
Language
English
PMID
2285828
DOI
10.1002/bms.1200191007
Web of Science Id
WOS:A1990EB66600006
Abstract
Several aminophenanthrenes have been examined with electron impact mass spectrometry. The trifluoroacetic anhydride (TFAA) and perfluoropropionic anhydride (PFPA) derivatives of 4-aminophenanthrene have been studied with electron impact as well as both positive and negative ion chemical ionization mass spectrometry utilizing methane as a reagent gas. The resulting mass spectra indicate a loss of water from the derivatives and a mechanism is proposed to account for this loss. The spectra also indicate unique fragmentation patterns associated with the position of the substituent, particularly the four position which is in the region of the molecule termed the bay region. Another interesting aspect is the spectral differences observed for the TFAA and PFPA derivatives of 4-aminophenanthrene. The positive ion chemical ionization mass spectrum of the TFAA derivative indicates an ion [M + H - H2O]+; however, the mass spectrum of the PFPA derivative of 4-aminophenanthrene indicates no water loss from the [M + H]+ ion. The negative ion chemical ionization mass spectra of the two derivatives are also very different. The mass spectrum of the TFAA derivative shows an [M - 18]- ion and the PFPA derivative shows successive losses of HF with no apparent loss of water.
Keywords
Mass Spectrometry/methods; Phenanthrenes/chemistry
Tags
PFAS
•
Additional PFAS (formerly XAgency)
•
Expanded PFAS SEM (formerly PFAS 430)
Litsearch: September 2019
PubMed
ToxNet
Not prioritized for screening
Trifluoroacetic anhydride
•
^Per- and Polyfluoroalkyl Substances (PFAS)
PFPeA (2706-90-3)
Literature Search
Pubmed
•
PFAS 150
Literature Search Update December 2020
PubMed
Literature Search August 2019
PubMed
ToxNet
Not prioritized for screening
Pentafluoropropanoic anhydride
Perfluoropropanoic acid
•
PFPeA
Literature Search
Pubmed
Screening Results
Excluded/Not on Topic
Home
Learn about HERO
Using HERO
Search HERO
Projects in HERO
Risk Assessment
Transparency & Integrity